Scope & Range of Services
1. Explosion and fire from spark-ignited solvent fumes.
Prepared technical report on solvent volatility, spread of fumes, and
source of ignition. Identified human errors.
2. Toxins spread from a leaking lagoon for chemical wastes.
Deposition testimony on process that produced chemical wastes, on
alternative methods of disposal, and exposures.
3. Personal injury to workers from factory lead fumes.
Analyzed air pollution data for plaintiff, prepared report, and
testified in jury trial on exposures and EPA/OSHA standards.
4. Fire spread by combustible vegetable oil in storage.
Prepared report on hazards of storage in relation to the spontaneous
combustion that is well known to persons trained in the field.
5. Patent infringement on a corrosion-protective coating.
Explained complex chemistry of process to distinguish between competing
patents. Prepared report and deposition.
6. Spontaneous combustion of a supermarket charcoal.
Explained mechanism of spontaneous combustion, prepared report on cause
and origin of fire.
7. Chemical wastes from leaks in pharmaceuticals plant.
Analyzed causes of underground leakage, alternative storage, and
process techniques.
8. Injuries from explosion in a pharmaceuticals plant.
Identified causes of explosion as well as the chemicals and process
techniques that produced hazard.
9. Fire caused by storage of combustible naphthalene.
Reported on flammability of naphthalene, its heating characteristics
and hazards, origins of massive fire.
10. Explosion and fire in a drum disposal facility.
Identified the source of a fire in a drum thought to be empty of a
flammable solvent.
EDUCATION
BS ChE (Magna Cum Laude), New York
University
Doctorate in Chemical Engineering,
Yale University
ACADEMIC
EXPERIENCE
University
of Pennsylvania
Professor of Chemical Engineering,
1967-present.
University Judicial Administrator,
1996-98.
University Ombudsman, 1990-93.
Acting Chairman, Department of Chemical
Engineering, 1985-86.
Chairman of Department of Chemical
& Biochemical Engineering, 1972-77.
Chairman of Graduate Group in Chemical
Engineering, 1969-72.
Acting Director, School of Chemical
Engineering, 1970-71.
University
of Rome, Italy, Department of Chemistry, Visiting Professor,
1987.
Casali
Institute of Applied Chemistry, Hebrew University of Jerusalem,
Visiting Professor, 1978 and 1987.
University
of Manchester (England), Institute of Science and Technology,
Visiting Professor, 1968-69.
Harvard
University, Research Fellow in Engineering, 1964-65.
University
of Illinois, Urbana, Assistant Professor, 1958-64.
INDUSTRY
EXPERIENCE
International
Institute for Applied Systems Analysis, Laxenburg, Austria,
Environmental Research, 1995.
Mobil Research & Development Corporation, Environmental
Protection, 1990.
Day & Zimmerman, Plastics Recycle, Bridgeport, NJ, 1990.
Dupont Company, Engineering R&D Division, Newark, DE,
1989.
Davison Chemical Division of W.R. Grace & Co., Baltimore,
MD; Unit Operations and Reactor Design, 1979-88.
Air Products and Chemical Co., Allentown, PA; Chemical Reactor
Design, Environmental Systems, 1973-78.
Rohm and Haas Chemical Company, Bristol, PA; Energy
Storage and Chemicals, 1974-76.
Exxon Research and Engineering Co., Florham Park, NJ; Reactor
Design, 1965-68, 1976.
Firestone Chemical Company, Pottstown, PA; Automatic Control,
July 1966.
USI Chemicals, Tuscola, IL; Stability Problems of High Pressure
Chemical Reactors, 1963-64.
Phillips Petroleum Co., Bartlesville, OK; Reactor Design and
Stability, April, 1963.
Staley Manufacturing Co., Decatur, IL; Control of Chemical
Process Systems, 1961-62.
Shell Development Company, Process Optimization, 1961.
Esso Research and Engineering Co., Research and Development,
1955-58.
HONORS
AND FELLOWSHIPS
Lindbach
Award for Distinguished Teaching, University of Pennsylvania.
Fellowship at the National Research Council, Rome, Italy.
Forschheimer Chair at Hebrew University, Jerusalem.
Harry Pierce Chair at The Technion-Israel Institute of Technology.
Dodge Lecturer at Yale University.
Prize from Quest for Technology, Wharton School, University
of Pennsylvania.
American Society for Engineering Education, Award for outstanding
contributions to education.
Fulbright Lecturer, University of Zagreb, Yugoslavia.
Fulbright Senior Research Fellow, University of Manchester,
England.
Guggenheim Fellowship, Harvard University.
Elected to New York Academy of Science.
Ford Foundation Faculty Development Grant.
Higgins Fellow at Yale University.
Elected to Sigma Xi honorary.
Elected to Tau Beta Pi honorary.
PROFESSIONAL
MEMBERSHIPS
American Institute of Chemical Engineers
American Society of Engineering Education
American Association for Advancement of Science
REVIEW
PANELS
U. S. Civilian Research and Development Foundation,
Proposal Review, March, 2003.
U. S. Department of Energy, NETL Review Panel on Vision 21
Advanced Coal Research.
U. S. Department of Energy, Energy Technology Center, Review
Panel on Environmental Research.
National Science Foundation, Panel on Engineering Research
Centers.
U. S. Department of Energy, Pittsburgh Energy Technology Center,
Review Panel on Coal Research.
National Science Foundation, Panel on Specialized Research
Equipment.
Technical Reviewer, Office of Technology Assessment, U.S.
Congress.
National Science Foundation, Review Panel on Initiation Grants.
Ames Laboratory Review Panel on Chemical Science.
International Programs Panel on Energy Problems in UN Least
Developed Nations.
U.S. Department of Energy Review Panel on Processes for Thermochemical
Hydrogen.
Panelist on Environmental Problems, New York Section AIChE.
RESEARCH
SPECIALIZATIONS
Chemical Reactor Design; Kinetics of Gas-Solid Reactions
Environmental and Energy Problems
Automatic Control, Stability, and Optimization
PUBLICATIONS
Books:
1.
"Introduction to Chemical Process Control," John Wiley
& Sons, New York (1965). Also reprinted by
Robert E. Krieger Publishing Co., Huntington, NY (1975); an
undergraduate-level text on automation for chemical engineers.
2. "Stability of Chemical Reactors," Prentice-Hall, Englewood
Cliffs, NJ (1972); a graduate-level textbook and
research monograph.
3. "Informed Choice: A Citizen's View of Environmental
Protection," The Copy Center, SEAS, University of Pennsylvania
(1995); an undergraduate-level text on energy and environment.
Journal
Papers, Patent:
1.
"Effect of High Pressure Hydrogen Gas on Metals," Ind.
Eng. Chem., 48, 885 (1956) (with B.F. Dodge).
2. "Surface-Renewal Models in Mass Transfer," Chem.
Eng. Sci., 16, 287 (1961).
3. "Systems Engineering," Chem. Eng. Prog., 58, No.
5, 42 (1962).
4. "A Stirred Reactor for Surface-Catalyzed Kinetics,"
Chem. Eng. Prog., 58, No. 12, 45 (1962) (with F.E. Ford).
5. "Mass Transfer Effects in Surface Catalysis," AIChE
Journal , 9, 371 (1963) (with F.E. Ford).
6. "An Interpretation of Experimental Results in Sonic
Chemical Analysis,"AIChE Journal, 9, 422 (1963) (with I.A.
Gura).
7. "Effects of Solute Purity, Temperature, and Surfactants
on Solid-Liquid Mass Transfer," AIChE Journal, 9, 474 (1963)
(with D.N. Ghosh).
8. "Chemical Reactor Stability by Liapunov's Direct
Method," AIChE Journal, 10, 253 (1964) (with J.S.Berger).
9. "The Effect of Feedback Control on Chemical Reactor
Stability," AIChE Journal, 10, 238 (1964) (with J.S.
Berger).
10. "The Kinetics of the Brass-Catalyzed Dehydrogenation of
Sec-Butyl Alcohol," Chem. Eng. Sci., 19, 371 (1964)
(with F.E. Ford).
11. "The Stability of Cascaded Reactors," Ind. Eng. Chem.
Fund., 4, 90 (1965) (with J.S. Berger).
12. "An Extended Region of Asymptotic Reactor Stability,"
Chem. Eng. Sci., 20, 1974 (1965) (with J.S. Berger).
13. "Stability of Nonlinear Systems in the Region of Linear
Dominance," AIChE Journal, 11, 474 (1965) (with I.A.
Gura).
14. "The Use of Experimental Data in Design of Multi-Variable
Control," Ind. Eng. Chem. Fund, 4, 481 (1965) (with W.O. Paradis).
15. "Systematic Determination of Practical Stability
Regions for Non- Linear Systems," Preprint 65-WA/AUT- 19
of ASME Meeting, Chicago, Nov.10, 1965 (with I.A. Gura).
16. "Tracking Function Approach to Practical Stability
and Ultimate Boundedness," AIChE Journal, 12, 130 (1966)
(with W. O. Paradis).
17. "The Application of the Midas Digital Simulator
to the Study of Kinetic Alternatives in a Chemical Reaction
System," Simulation, 6, 192 (1966) (with T. Z. Fahidy).
18. "Dynamics of a Surface-Catalyzed Chemical System,"
Can. J. Chem. Eng., 44, 95 (1966) (with T. Z. Fahidy).
19. "Optimality and Computational Feasibility in Transient
Control. Part I: Modified Criterion for Optimality,"
AIChE Journal, 12, 876 (1966) (with W. O. Paradis).
20. "Optimally and Computational Feasibility in Transient
Control. Part II: Feedback Control of a Distributed
Parameter Process," AIChE Journal, 12, 883
(1966) (with W. O. Paradis).
21. "The Stability of A Plug Flow Tubular Reactor Under
Feed-Forward and Recycle Control," Proc. Joint Automatic
Control Conference, p. 107, Philadelphia, June 1967 (with
F. S. Wang).
22. "A Composite Phase Plane for Tubular Reactor Stability,"
AIChE Journal, 14, 335 (1968) (with F. S. Wang).
23. "A Stirred Reactor with Porous Catalyst Wall," Ind.
Eng. Chem. Proc. Design and Development, 7, 261 (1968)
(with D. L. Relyea).
24. "Bounding Chemical Reactor Transients by Estimation
of Growth or Decay Rates," AIChE Journal, 14, 934 (1968)
(with F. S. Wang).
25. "Comparison of Two Methods Used in Analysis of Reactor
Dynamics," AIChE Journal, 14, 335 (1968) (with F. S.
Wang).
26. "A Comparison of Several Techniques in Local Stability
Analysis," Chem. Eng. Journal, 2, No. 2, 125 (1971)
(with C. R. McGowin).
27. "Tubular Reactor Steady State and Stability Characteristics
- I: Effect of Axial Mixing," AIChE Journal, 17, 831 (1971)
(with C. R. McGowin).
28. "Tubular Reactor Steady State and Stability Characteristics
- II: Limiting Behavior and Collocation Solution of the Radial
Mixing Case," AIChE Journal, 17, 837 (1971) (with C.
R. McGowin).
29. "Tubular Reactor Steady State and Stability Characteristics
- III: Effect of Recycle," AIChE Journal, 17,
842 (1971) (with C. R. McGowin).
30. "Regions of Asymptotic Stability for Distributed
Parameter Systems," Chem. Eng. Sci., 26, 275 (1971) (with
C. R. McGowin).
31. "Constrained and Weighted Least Squares Procedures
for Parameter Estimation," Ind. Eng. Chem. Fund., 10, 150
(1971) (with R. E. Vallerschamp).
32. "Stability of Time-Delay Systems," AIChE Journal,
18, 380 (1972) (with J. G. Landis).
33. "Stability of Chemical Reactors: Some Practical
Considerations," Indian Chem. Eng., 15, No. 2, 17 (1973).
34. "An Uncoupling Technique for the Study of Multivariable
Nonlinear Time-Delay Systems," Ind. Eng. Chem. Fund.,
12, 476 (1973) (with J. G. Landis).
35. "Regional Stability for a Tubular Reactor with Axial
Mixing," Can. Journal Chem. Eng., 49, 274 (1974) (with
F. S. Wang). 36. "A Unified Treatment of the Inlet Boundary
Condition for Dispersive Flow Models," Chem. Eng. Sci., 31, 250
(1976) (with C. Y. Choi).
37. "Effects of Immobilization on the Kinetics of Enzyme-Catalyzed
Reaction: Part 1: Glucose Oxidase in a Recirculation
Reactor System," Biotechnology & Bioengineering, 18, 669
(1976) (with K. B. Ramachandran).
38. "Effects of Immobilization on the Kinetics of Enzyme-Catalyzed
Reaction: Part 2: Urease in a Packed Bed Differential
Reactor System," Biotechnology & Bioengineering,
18, 685 (1976) (with K. B. Ramachandran).
39. "The Oxidation of Bituminous Coal: Part 1: Development
of a Mathematical Model," Chem. Eng. Sci., 31, 815 (1976)
(with A. N. Hixson and A. Y. Kam).
40. "The Oxidation of Bituminous Coal: Part 2: Experimental
Kinetics and Interpretation," Chem. Eng. Sci., 31, 821
(1976) (with A. N. Hixson and A. Y. Kam).
41. "The Oxidation of Bituminous Coal: Part 3: Properties,"
Ind. Eng. Chem. Proc. Design and Dev., 15, No. 3, 416
(1976) (with A. N. Hixson and A. Y. Kam).
42. "Activator Effects of Urease Kinetics," AIChE Journal,
22, 1106 (1976) (with C. Y. Choi).
43. "Pyrite Oxidation in Aqueous Ferric Chloride," AIChE
Journal, 23, 679 (1977) (with W. E. King, Jr.).
44. "Optimal Catalyst Distribution in a Dual-Enzyme
Sequential System," AIChE Journal, 23, 319 (1977) (with
C. Y. Choi).
45. "On Singular Policies in the Optimal Distribution
of a Bifunctional Catalyst: Part 1: Effects of Reaction Kinetics,"
AIChE Journal, 24, 193 (1978) (with C. Y. Choi).
46. "Recycle Effects on the Distribution of ATP Regeneration
Catalysts," AIChE Journal, 24, 735 (1978) (with C.
Y. Choi).
47. "On Singular Policies in the Optimal Distribution
of a Bifunctional Catalyst: Part 2: Effect of Diffusional and
Mass Transfer Resistances," AIChE Journal, 24, 200 (1978)
(with C. Y. Choi).
48. "Optimal Contaminant Removal in Fermentation and
Waste Treatment Processes," Automatica, 14, 325 (1978)
(with C.Y. Choi).
49. "Reactor Design from a Stability Viewpoint," Chem.
Eng. Educ., 12 , 168 (1978).
50. "A Population Balance Approach to the Modeling of
Solid Phase Reactions," AIChE Journal, 25, 298 (1979)
(with S. K. Bhatia).
51. "On the Kinetics of Coal Oxidation," AIChE Journal,
25, 773 (1979) (with N. L. Avison and R. M. Winters).
52. "The Mixing of Granular Solids in a Rotary Cylinder:
A Staged Surface-Renewal Model," AIChE Journal, 26, 928
(1980) (with J. Mu).
53. "A Random Pore Model for Fluid-Solid Reactions:
Part I: Isothermal Kinetic Control," AIChE Journal,
26, 379 (1980) (with S. K. Bhatia).
54. "An Equilibrium-Interface Model for Solid Decomposition
Reactions," Chem. Eng. Sci., 34, 1645 (1980) (with J.
Mu).
55. "The Mixing of Granular Solids: Part II: Experimental
Results and Parameter Estimation," Inst. Chem. Engrs.
Symp. Ser., No. 59, p. 5:7/1 (1980) (with J. Mu).
56. "A Simulation Study of Rotary Reactor Performance,"
Chem.Engg .Comm., 9, 101 (1981) (with J. Mu).
57. "The Effect of Pore Structure on Fluid-Solid Reactions:
Applications to the SO2-Lime Reaction," AIChE Journal, 27,
226 (1981) (with S. K. Bhatia).
58. "Salt Hydrates as Absorbents in Heat Pump Cycles,"
Solar Energy, 26, (4) 333 (1981) (with M. A.Stanish).
59. "A Random Pore Model for Fluid-Solid Reactions:
Part II: Diffusion and Transport Effects," AIChE Journal, 27,
247 (1981) (with S. K.Bhatia).
60. "Thermal Decomposition of Inorganic Sulfates and
Their Hydrates," Ind. Eng. Chem. Proc. Design and Development, 20,
640 (1981) (with J. Mu).
61. "A New Look at an Old Fossil: Kinetics of Coal Processing,"
Chem. Eng. Education, 15, No. 1, 14 (1981).
62. "Thermal Decomposition of Carbonates, Carboxylates,
Oxalates, Acetates, Formates, and Hydroxides," Thermochimica
Acta, 49, 207 (1981) (with J. Mu).
63. "Reaction Regimes in Coal Oxidation," AIChE Journal,
27, 920 (1981) (with G. G. Karsner).
64. "Pyrolytic Effects on Swelling and Pore Structure
of Bituminous Coals," Chapter 1-3 in Alternative Energy Sources,
Vol. 6, p. 31, Ann Arbor Science Publishers (1982) (with J.
M. Vargas).
65. "Kinetics of Coal Drying-Decomposition," AIChE Journal,
28, 199 (1982) (with G. G. Karsner).
66. "A Model for Coal Oxidation Kinetics. Part 1: Reaction
Under Chemical Control," Fuel, 61, 29 (1982) (with
G. G. Karsner).
67. "A Model for Coal Oxidation Kinetics. Part 2: An
Effectiveness Factor Interpretation," Fuel, 61, 35 (1982) (with
G. G. Karsner).
68. "Effects of Drying and Oxidation on Coal Pore Structure,"
Ind. Eng. Chem. Proc. Design and Development, 21, (2),
348 (1982) (with G. G. Karsner).
69. "Thermal Decomposition of Metal Nitrates and Their
Hydrates," Thermochimica Acta, 56, 253 (1982) (with J.
Mu).
70. "Effect of the Product Layer on the Kinetics of
the CO2-Lime Reaction," AIChE Journal, 29, 79 (1983) (with
S. K. Bhatia).
71. "Unified Treatment of Structural Effects in Fluid-Solid
Reactions," AIChE Journal, 29, 281 (1983) (with S. K.
Bhatia).
72. "Kinetics and Transport Effects in the Dehydration
of Crystalline Potassium Carbonate Hydrate," AIChE Journal,
29, 806 (1983) (with M. A. Stanish).
73. "Comparison of TGA with Bench-Scale Rotary Reactor
Studies," Chem. Eng. Res. Des. (Trans. Institution Chem.
Engrs.), 61, 198 (1983) (with J. Mu).
74. "Rate Processes in Cycling a Reversible Gas-Solid
Reaction," AIChE Journal, 30, 56 (1984) (with M. A. Stanish).
75. "Kinetics of Hydration-Dehydration Reactions Considered
as Solid Transformations," AIChE Journal, 30, 557
(1984) (with M. A. Stanish).
76. "Simulation of Pore Growth and Coalescence," AIChE
Journal, 30, 829 (1984) (with J.-L. Su).
77. "Evolution of Pore Volume Distribution During Gasification,"
AIChE J., 30, 967 (1984) (with J.-L. Su).
78. "Modification of Petersen's Model for Porous Solids,"
AIChE Journal, 31, 343 (1985).
79. "Effect of Pore Structure on Particle Ignition During
Exothermic Gasification Reactions," AIChE Journal, 31,
157 (1985) (with J.-L. Su).
80. "Effect of Pore Structure on Char Oxidation Kinetics,"
AIChE Journal, 31, 973 (1985) (with J.-L. Su).
81. "Porosity Effects on Catalytic Char Oxidation.
Part 1: A Catalyst Deposition Model," AIChE Journal, 31, 957
(1985) (with J.-L. Su).
82. "Porosity Effects on Catalytic Char Oxidation.
Part 2: Experimental Results," AIChE Journal, 31, 965 (1985)
(with J.-L. Su).
83. "Effect of Chemisorbed Oxygen on Char Reactivity,"
AIChE Journal, 31, 1725 (1985) (with J.-L. Su).
84. "An Interpretation of Coal Pyrolysis Kinetics,"
Ind. Eng. Chem. Proc. Design and Development, 25, 49 (1986)
(with J. M. Vargas).
85. "Self Heating and Spontaneous Combustion," Proc.
Conference on Gas-Solid Reactions in Pyrometallurgy, W.
Lafayette, Indiana, Session 2, April 24-25, 1986.
86. "Pore Structures and Kinetics in the Thermal Decomposition
of Al(OH)3," AIChE Journal, 32, 1532 (1986) (with
L. Candela).
87. "Effect of Pore-Distributed Coke on Catalyst Regeneration
Kinetics," AIChE Journal, 33, 940 (1987) (with Yuli
Chang).
88. "Diffusion Processes in the Doping of Polymer Films,"
Solid State Ionics, 27, 115 (1988) (with B. Scrosati).
89. "Catalyst Regeneration Kinetics in the Presence
of Pore Blockage," AIChE Journal, 35, 385 (1989) (with Yuli
Chang).
90. "Porosity Effects in H2 Reduction of Iron Oxides,"
AIChE Journal, 35, 1245 (1989). (with A. J. Fortini).
91. "Characteristics of Electrochemically Synthesized
Polymer Electrodes," J. Electrochem. Soc., 136 (12), 3729
(1989) (with S. Panero, P. Prosperi, S.
Passerini, and B. Scrosati).
92. "Sequential Gas-Solid Reactions with Application
to Iron Oxide Reduction," AIChE Journal, 35, 1975 (1989)
(with A.J. Fortini).
93. "The Effect of Pore Structure on the Char-H2O Reaction,"
AIChE Journal, 35, 1791 (1989) (with W-K.Chi)
94. "A Thin Film Model for Diffusion Controlled Electrochemical
Doping of Polymers," Chem. Eng. Sci., 45 (11),
3381 (1990) (with B. Scrosati).
95. "Inaccessible Porosity in Gasification Reactions
Under Kinetic Control," AIChE Journal, 37, 1607 (1991) (with
E. A. Delikouras).
96. "Diffusional Limitations on the Kinetics of Dehydration
Reactions of Hydrated Barium Chloride," Thermochimica
Acta , 202, 151-171 (1992) (with J. A. Lumpkin).
97. "Kinetics of Boehmite Formation by Thermal Decomposition
of Gibbsite," Ind. & Engg. Chem. Research, 31,
694 (1992) (with L. Candela).
98. "Combined Effects of Mass Transport and Inaccessible Porosity
in Gasification Reactions," AIChE Journal, 39, 829
(1993) (with E. A. Delikouras).
99. "Oxygen Diffusion and Reaction of Residual Carbon
in Sol-Gel Derived Silica," Journal Non-Cryst. Solids , 169,
183 (1994) (with P. A. Robinson).
100. "Characterization of PLZT Films Deposited by Spray
Pyrolysis," Journal Amer. Ceramic Soc., 77, No. 12, 3142
(1994) (with E. A. Delikouras).
101. "Thermal and Water Vapor Effects on the Rates of
the Dehydration Reactions of Barium Chloride," Thermochimica
Acta, 249, 335 (1995) (with J. A. Lumpkin).
102. "Liquid Phase Separation of Polar Hydrocarbons
from Light Aromatics Using Zeolites," Adsorption , 5, 399-407
(1999) (with A. G. Palkhiwala, Y.-H. Lin, and D. H. Olson).
103. Patent: "Deashing Polymers with Organic Cyanides",
U.S. Patent 3,010,952 (1962) (with J. R. Lovett and
J. M. Kelley). Assigned to Exxon Research and Engineering
Co.